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Photoelectron dynamics, chiral molecules

C. Photoelectron Circular Dichroism Photoelectron Dynamics in Chiral Molecules... [Pg.267]

An X-ray analysis 34a) of ( ),( ),( )-l,5,9-cyclododecatriene (38) suggested that this molecule is most comfortable in a twisted chiral conformation of D3 symmetry, and a dynamic NMR study and a force-field calculation Mb) estimated AG = 8.6 kcal/mol for the racemization process between two enantiomeric D3 conformers. A pseudochair conformation of similar D3 symmetry was also suggested35) for 1,5,9-cyclodo-decatriyne (39), following an ab initio STO-3G calculation and photoelectron spectroscopy. [Pg.7]


See other pages where Photoelectron dynamics, chiral molecules is mentioned: [Pg.275]    [Pg.282]    [Pg.289]   
See also in sourсe #XX -- [ Pg.275 , Pg.276 , Pg.277 , Pg.278 , Pg.279 , Pg.280 ]




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