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Phosphorus-metal coupling constants

Effect of trans and cis ligands on phosphorus-metal coupling constants... [Pg.368]

Phosphorus-metal coupling constants, c./sec., in complexes of phosphines R Ph3 P... [Pg.373]

Variation of some phosphorus-metal coupling constants with oxidation state... [Pg.374]

Figure 6.19 An example of the effect of 71 bonding on metal-phosphorus NMR coupling constants... Figure 6.19 An example of the effect of 71 bonding on metal-phosphorus NMR coupling constants...
Phosphorus—Phosphorus spin coupling constants through metal atoms have only been obtained recently. There are three distinct... [Pg.378]

Jpj- becomes smaller in magnitude (actually less negative) when the fluorophosphine becomes attached to the metal, and the remote phosphorus-fluorine coupling constant e/pp is usually less than 5 Hz in the cis complexes, but distinctly larger ( 30 Hz) in the trans derivatives 145, 322). [Pg.455]

Poraij-Koshits MA (1978) Structural effects of mutual influence of ligands in transition- and non-transition-metal complexes. Koordinatsionnaya Khimiya 4 842-866 (in Russian) Hartley FR (1973) The cis- and trans-effects of ligands. Chem SocRev 2 163-179 Russell DR, Mazid MA, Tucker PA (1980) Crystal structures of hydrido-tris(triethyl-phosphine)platinum(II), fluoro-tris(triethylphosphine)platinum(lD, and chloro-tris(trieth-ylphosphine)platinum(II) salts. J Chem Soc Dalton Trans 1737-1742 Blau R, Espenson J (1986) Correlations of platinum-195-phosphorus-31 coupling constants with platinum-hgand and platinum-platinum bond lengths. Inotg Chem 25 878-880 Belsky VK, Konovalov 1, Kukushkin VYu (1991) Structure of cis-dichloro-(dimethyl-sulfoxide)-(pyridine)platinum(II). Acta Cryst C47 292-294... [Pg.225]

This chapter emphasizes the establishment of trends in coupling constants between transition metals and phosphorus and the interpretation of such trends in terms of the appropriate molecular orbital (MO) treatments that are currently available. [Pg.10]

See other pages where Phosphorus-metal coupling constants is mentioned: [Pg.128]    [Pg.383]    [Pg.407]    [Pg.336]    [Pg.345]    [Pg.3]    [Pg.528]    [Pg.144]    [Pg.227]    [Pg.77]    [Pg.170]    [Pg.314]    [Pg.389]    [Pg.300]    [Pg.64]    [Pg.176]    [Pg.42]    [Pg.19]    [Pg.89]    [Pg.85]    [Pg.108]    [Pg.89]    [Pg.448]    [Pg.1013]    [Pg.9]    [Pg.12]    [Pg.13]    [Pg.14]    [Pg.16]    [Pg.25]    [Pg.25]    [Pg.41]    [Pg.493]    [Pg.25]    [Pg.131]    [Pg.455]    [Pg.103]    [Pg.44]    [Pg.122]    [Pg.127]    [Pg.1057]   


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One-Bond Metal-Phosphorus Coupling Constants

One-Bond Metal-Phosphorus Coupling Constants - A Survey

Phosphorus-31 couplings

Phosphorus: coupling constants

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