Phosphinimines synthesis from

Phosphinimato complexes transition metals, 122,125 bonding, 124 IR spectroscopy, 124 reactions, 125 structure, 124 synthesis, 123 Phosphinimines imido metal complexes synthesis from, 167 Phosphoglucomutase zinc complexes, 965 Phospholes... 

Synthesis of a CO Sensing Molecule. Complex lc was isolated as a microcrystalline solid from the reaction of ferrocenyl phosphinimine, FcN=PPh3 and Fe2(p-CH2)(CO)8,(24) and has spectral features similar to la and lb, equation (2). (12-13) FTIR shows that 1 mM lc is converted rapidly (t1y2< 1 min) and quantitatively to 2c upon exposure to 1 atm of CO in THF solution, and it also confirms that the same chemistry occurs in a thin film of MEEP/Li[CF3S03] at 298 K, Figures la and lb respectively. 

A novel solid phase method for the synthesis of 2 -amino-2 -deoxynucleoside 5 -triphosphates has been developed in which the 3 -azidonucleoside precursors are first linked to support-bound triphenylphosphine as their phosphinimines 116. Following conversion into the triphosphate, the desired 2 -amino-2 -deoxy-nucleoside 5 -triphosphates are released from the support by treatment with ammonia in the Staudinger reaction. ... 

Barluenga and co-workers have reported the synthesis of 1,5,2A -diazaphosphinin-6-ones (184) by cyclization of the enamino-phosphinimines (183). These are prepared from the alkyldiphenyl-phosphinimines (182) as indicated in Scheme 35 <87TL2875,89JCS(P1)615>. 

Pinter and co-wokers [80] described the synthesis of bicyclic trans-fused glucopyranoso-oxazolidinone 73 and the galacto isomer by reaction of the corresponding glycopyranosyl phosphinimines with carbon dioxide (Scheme 18). A one-pot procedure to prepare 73 from glucopyranosyl azide 70 in high yield (97%) has been described recently [81]. 

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