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Phosphinic acid derivatives, selective bond

With chiral ligands the Heck reaction can be enantioselective. The amino-acid-derived phosphine ligand in the margin controls the Heck reaction of phenyl triflate with dihydrofuran. The ligand selects one enantiotopic face of the alkene (see Chapter 45 if you have forgotten this term) and the usual double bond migration and (5 elimination complete the reaction. [Pg.1326]


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Bond-selectivity

Bonded Derivatives

Bonding derivatives, acidity

Bonds selection

Phosphine bonding

Phosphine derivatives

Phosphine derivatives, acidity

Phosphines acids

Phosphines phosphinic acids

Phosphines, £-selectivity

Phosphinic acid

Phosphinic acid derivatives

Phosphinous acids

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