Phosphine, iridium complex triphenyl

C1bHi5As, Arsine, triphenyl-iron complex, 26 61 C H 5OjP, Triphenyl phosphite ruthenium complex, 26 178 CuHijP, Phosphine, triphenyl-cobalt complex, 26 190—197 cobalt-gold-ruthenium, 26 327 gold complex, 26 90, 325, 326 gold-manganese complex, 26 229 iridium complexes, 26 117-120, 122-125, 201, 202... 

PC8HM, Phosphine, dimethylphenyl-, 22 133 iridium complex, 21 97 PC 2H27, Phosphine, tributyl-, chromium complexes, 23 38 PC18H1S, Phosphine, triphenyl-, 21 78 23 38 cobalt complexes, 23 24-25 cobalt, iridium, and rhodium complexes, 22 171, 173, 174 iridium complex, 21 104 palladium complex, 22 169 palladium and platinum complexes, 21 10 ruthenium complex, 21 29 PNOC 2Hl2, Phosphinic amide, diphenyl-, lanthanoid complexes, 23 180 PNAH.2, Propionitrilc, 3,3, 3 -phosphinidy-netri-,... 

PQH, Phosphine, dimethylphenyl-, 22 133 iridium complex, 21 97 PC 8Hi3, Phosphine, triphenyl-, 21 78 cobalt, iridium, and rhodium complexes, 22 171, 173, 174 iridium complex, 21 104... 

Although oxidation reactions of this type are generally associated with square-planar four-co-ordinate complexes, there are several examples of oxidative addition to five-co-ordinate species. In these systems, however, the mechanism may also be termed as oxidative elimination since the product is six co-ordinate and one of the ligands is displaced. The mechanism of silicon hydride addition to hydridocarbonyltris(triphenyl-phosphine)iridium(i) has been described, the reaction... 

BCIF4I1OP2C37H3, Iridium(ll), carbonyl-chlorohydrido[tetrafluoFoborato(l - ))-bis(triphenylphosphine)-, 26 117,28 23 BClF4lrOP2C3gH33, Iridium(III), carbonyl-chloromethyl[tetrafluoroborato(l—)]-bis( triphenylphosphine)-, 26 118,28 24 BF4, Borate(l—), tetrafluoro-, molybdenum and tungsten complexes, 26 96-105 BF4AuIr3N03P7C,gH,3, Borate(l-), tetrafluoro-, tris[l,2-ethanediylbis(diphenyl-phosphine)]hexahydrido[(triphenyl-phosphine)gold]triiridium(2+) nitrate (1 1 1), 29 291... 

Dimethyl H-phosphonate oxidatively adds to Ir (I) and Rh (I) compounds with the formation of hydrido-fr(ni) and hydrido-Rh(lII) phosphonato complexes [439]. Treatment of chloro-bis(cyclooctadiene) iridium (I) [IrCl(C8Hj4)2]2 with two equivalents of triphenyl phosphine and subsequent reaction with dimethyl H-phosphonate affords two products of oxidative addition I and II, which have not been spectroscopically distinguished ... 

An important feature of the iridium phosphine class of complexes is that the triphenyl-phosphine hgands can be replaced with a wide variety of phosphine and related donor... 

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