Phosphazanes with P-N-C Linkages

Substituted amino phosphines can be made by reactions between phosphorus trihalides and secondary amines. [Pg.510]

phosphorus trichloride reacts with dimethylamine to produce tris dimethylaminophos-phine, (Me2N)3P. This compound can also be obtained by cleavage of the Sn-N or the Si-N bond. [Pg.511]

The P-N bond is cleaved below room temperature by the action of hydrogen halides and boron halides. [Pg.511]

Tris(dimethylamino)phosphine undergoes trani-esteriflcation reactions with alcohols (7.84), with phenyl azide a monophosphazene is produced (7.448). [Pg.511]

Tris(dialkylamino)phosphines form various complexes with metal salts which contain a metal-phosphorus linkage, such as (Me2N)3P Cdl2, (Me2N)jP Ni(CO)3 and (Me2N)3P)2 W(CO)4 (Chapter 8). [Pg.511]

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