Phenylsilicon trichloride

In the early part of my paper, I referred to the work of Voronkov j[3] regarding the physiological effects observed by him for a series of organosilicon compounds. A particularly intriguing observation was the high mammalian toxicity of the compound phenylsilatrane. This compound can easily be obtained from phenylsilicon trichloride and triethanolamine ... 

SYNS PHENYLSILICON TRICHLORIDE PHENYL TRICHLOROSILANE pOT) SILICON PHENYL TRICHLORIDE... 

Phenyltriethylsiiicane is produced when phenylsilicon trichloride and zinc ethyl, in equal quantities, are heated in a sealed tube for one hour at 150° C. The gas pressure in the tube is then released and the heating continued at 160° C. and finally at 165° C. After treating the product with water, and then hydrochloric acid, an oil is formed which is taken up in ether, washed, dried, and distilled. The product, B.pt. 230° C., is phenyltriethylsiiicane, a colourless, faintly fuming liquid, soluble in ether and insoluble in water. It burns with a sooty fiame and has a density of 0 9042 at 0° C. Diphenyldiethylsilicane, B.pt. 305° to 315° C., is formed as a by-product ... 

Synonyms Phenylsilicon trichloride Phenyltrichlorosilicane Silane, phenyltrichloro- Silane, trichlorophenyl- Silicon phenyl trichloride Trichlorophenylsilane Empirical CeHsCIsSi... 

In Figure 84 is shown a chromatogram of a mixture of silicon tetrafluoride, phenylsilicon trifluoride and phenyl methyl silicon difluoride obtained by fluorination of a mixture of phenyl methyl silicon dichloride and phenyl silicon trichloride. 

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