Phase separation, in polymer solutions

Figure A2.5.27. The effective coexistence curve exponent P jj = d In v/d In i for a simple mixture N= 1) as a fimction of the temperature parameter i = t / (1 - t) calculated from crossover theory and compared with the corresponding curve from mean-field theory (i.e. from figure A2.5.15). Reproduced from [30], Povodyrev A A, Anisimov M A and Sengers J V 1999 Crossover Flory model for phase separation in polymer solutions Physica A 264 358, figure 3, by pennission of Elsevier Science.

Povodyrev A A, Anisimov M A and Sengers J V 1999 Crossover Fiery model for phase separation in polymer solutions Physica A 264 345-69... 

Case Study 1 Flow-induced Phase Separation in Polymer Solutions... 

C. Rangel-Nafaile, A. Metzner, K. Wissbrun, Analysis of stress-induced phase separations in polymer solutions, Macromolecules, 17,1187 (1984). 

Dobry, A. Boyer-Kawenoki, F., "Phase Separation in Polymer Solutions," J. Polym. Sci., 2, 90 (1947). 

Emmerik, P. T. van Smolders, C. A., "Phase Separation in Polymer Solutions. I. Liquid-Liquid Phase Separation of PPO Poly(2,6-dimethyl 1,4-phenylene oxide) in Binary Mixtures with Toluene and Ternary Mixtures with Toluene and Ethyl Alcohol," J. Polym. Sci., Part C., 21, 73 (1972). 

Rangel-Nafaile, C Metzner, A. B. Wissbrun, K. F., "Analysis of Stress-Induced Phase Separations in Polymer Solutions," Macromolecules, 17, 1187 (1984). 

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