Phase equilbria

Benedict-Webb-Rubin equation 252. 256-7 benzene, vapor pressure 260-1 benzene + I, 4-dimethylbenzene mixture, phase equilbria 420-2, 424... 

Randall, M. 1. 264. 265 Raoult s law 268-73 and phase equilbria 419. 423 standard state 289 Rectilinear diameters, law of 393 Redlich-Kister equation 220, 362 Redlick-K wong equation 256 relative apparent molar enthalpy of solutions 356-7... 

J. Nyvlt, Solid—Liquid Phase Equilbria, Elsevier Scientific Publishing Co., New York, 1977. 

Muan, A Osborne, E. F. Phase Equilbria Among Oxides in Steelmaking, Addison-Wesley Publishing Co., Reading, Mass. 1965. 

Table 7. Comparison of temperature estimates (°C) from stable isotopes, phase equilbria, and fluid inclusions... 

The next modification you will try allows phase equilibrium in the separator where most of the ammonia is condensed. For simplicity, though, you should set the conversion per pass in the reactor to 25 percent Change the separator so that it is a phase separation. The A -values are nitrogen, 4.8 hydrogen, 70 ammonia, 0.051 carbon dioxide, 0.32. (Remember that the symbol K value is used in both chemical reaction equilbria and phase equilibria, but K represents different things in those two cases.) The flow rates of nitrogen and hydrogen into the process are 1 and 3 mol per time unit, respectively, but there is also 0.01 mol per time unit of carbon dioxide. Because of the carbon dioxide,... 

Molecular modeling calculations have been carried out on a simple analog of CYANEX 301 (H2P(S)SH), and confirmed that the structures of the complexes consist of tetrahedral Co(H2P(S)S)2 and octahedral Ni(H2P(S)S)2(H20)2 [20], as shown in Figure 4. Vapor pressure osmometry measurements showed that the CYANEX 301 complexes are present in the organic phase as [C0L2] and [NiL2(H20)2] [7]. In contrast to CYANEX 272, CYANEX 301 does not exist as dimers in the organic phase [7], therefore, the extraction equilbria are different (Eqn.2 and Eqn. 3) ... 

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