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Perturbative Solution to the Coupled-Cluster Equations

scribe here how Eq. (4.19) may be solved in a manner that shows the connection between the CC and the MBPT approaches. We solve [Pg.95]

Inserting this value of into the CC expression for the total energy as given in Eq. (4.16) yields [Pg.96]

This expression is nothing but the result obtained in second-order perturbation theory, which is written explicitly in Eq. (3.38). [Pg.96]

The iterative process carried out when determining the cluster amplitudes from Eq. (4.19) may be continued by inserting the cluster amplitudes from one iteration into the right-hand side of Eq. (4.19) to obtain the new ampli- [Pg.96]


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