Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Perturbation by a broad intruder level

The formal K matrix theory for a Rydberg manifold perturbed by a broad intruder state was setup by Lane [393]. The results have been related in detail to the (/-reversal problem by Connerade et al. [380], whose [Pg.289]

When an extra level B is added to a series of levels labelled by n, then the K-matrix has the form [Pg.290]

For a general set of levels n which are arbitrarily spaced, as occur in [Pg.290]

We now discuss a problem involving two open channels a strongly coupled particle channel a and a weakly coupled radiative channel 7, so that Kai and Kyy are of first and second order of smallness respectively. It turns out that the exact result can be specialised to yield the S-matrix  [Pg.291]

If the radiative widths Tg and Hy are very small and the background constant Kay is neglected, then the formula simplifies to the following useful expression  [Pg.291]


See other pages where Perturbation by a broad intruder level is mentioned: [Pg.288]    [Pg.289]    [Pg.291]   


SEARCH



A levels

Broad

Broadness

© 2024 chempedia.info