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Peroxyphosphates allylic oxidation

The Kharasch-Sosnovsky reaction may be carried out in the presence of carboxylic acids to introduce the acyloxy moiety of the acid used, and may also be conducted photochemically at room temperature using UV irradiation. Peioxy acids,diacyl peroxides, and peroxyphosphates and peroxyphospho-nates are alternative oxidants. /-Butyl hydroperoxide may also be used in place of peroxy esters with broadly similar results, although formations of mixed peroxides and /-butyl ethers can then compete with allyl ester production. [Pg.96]


See also in sourсe #XX -- [ Pg.96 ]

See also in sourсe #XX -- [ Pg.96 ]

See also in sourсe #XX -- [ Pg.7 , Pg.96 ]

See also in sourсe #XX -- [ Pg.7 , Pg.96 ]




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Allyl oxide

Allylic oxidation

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