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Peroxycarboxylic acid esters

The RP-HPLC method based on the CL reaction of luminol (124) catalyzed by Co(II) (Section in.B.2.c) can be applied for determination of peroxycarboxylic acids, esters and diacyl peroxides (see examples of LOD in equation 67, Section V.B.2.c) . The biosensor prepared according to equation 70, that is effective in the determination of hydroperoxides (Section V.B.6.b), becomes deactivated after three days of operation when trying to determine t-butyl peracetate. ... [Pg.700]

Peroxycarboxylic acid esters are utilized as initiators for radical polymerization and are interesting intermediates for the decarboxylation of carboxylic acids. They are generally prepared by the acylation of hydro peroxides with acid chlorides, acid anhydrides, or imidazolides in the presence of a base. Condensation of carboxylic acids (20) with /-butyl-hydroperoxide (21) has been smoothly achieved by the use of diethyl phophorocyanidate and NEt3 under mild conditions giving f-butyl peroxycarboxylates (22) in good yield.9... [Pg.502]

Peroxycarboxylic acid esters from hydroperoxides CO Cl COOgR... [Pg.447]

See other pages where Peroxycarboxylic acid esters is mentioned: [Pg.698]    [Pg.701]    [Pg.698]    [Pg.701]    [Pg.275]    [Pg.89]    [Pg.457]    [Pg.299]    [Pg.266]    [Pg.352]    [Pg.62]    [Pg.70]    [Pg.227]    [Pg.321]    [Pg.250]   


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Peroxycarboxylic acids

Peroxycarboxylic esters

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