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Peroxides, organic, radiation-induced reactions

VinyUdene fluoride can be polymerized in saturated fluorinated or fluorochlorinated solvents. These solvents dissolve fluoroalkenes like vinylidene fluoride and organic peroxide catalysts. Polymerization thus takes place in a homogeneous phase and the resulting poly-vinylidene fluoride is insoluble in the solvent, making the product readily separable from the solvent. In addition to organic peroxides, the reaction can be initiated or induced by radiation. This is helpful in avoiding contamination of the product with other reaction components such as the initiator, surfactant, and the others. Alkyl boron activated by oxygen has also been reported to catalyze vinylidene fluoride and vinyl fluoride polymerization in water and solvents. ... [Pg.88]

See other pages where Peroxides, organic, radiation-induced reactions is mentioned: [Pg.921]    [Pg.922]    [Pg.921]    [Pg.922]    [Pg.466]    [Pg.1825]    [Pg.275]    [Pg.669]    [Pg.955]    [Pg.955]    [Pg.1610]    [Pg.1233]    [Pg.60]    [Pg.374]   


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Inducing reaction

Organic peroxides

Peroxidation reactions

Peroxides, organic, radiation-induced

Radiation reaction

Radiation-induced reactions

Reaction peroxide

Reactions induced

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