Perovskite membranes oxidative coupling

J.E. ten Elshof, H.J.M. Bouwmeester and H. Verweij, Oxidative Coupling of Methane in a Mixed-Conducting Perovskite Membrane Reactor , Appl. Catal. A, 130 195-212 (1995). 

Some dense inorganic membranes made of metals and metal oxides are oxygen specific. Notable ones include silver, zirconia stabilized by yttria or calcia, lead oxide, perovskite-type oxides and some mixed oxides such as yttria stabilized titania-zirconia. Their usage as a membrane reactor is profiled in Table 8.4 for a number of reactions decomposition of carbon dioxide to form carbon monoxide and oxygen, oxidation of ammonia to nitrogen and nitrous oxide, oxidation of methane to syngas and oxidative coupling of methane to form C2 hydrocarbons, and oxidation of other hydrocarbons such as ethylene, methanol, ethanol, propylene and butene. 

So far, there are only a few reports of perovskite hollow fiber membrane reactors in the oxidative coupling of methane. Tan and Li studied the catalytic perovskite Lao.6Sro.4Coo.2Feo.8G3 (LSCF) hollow fiber membrane as... 

Lin Y S and Zheng Y (1996), Catalytic properties of oxygen semipermeable perovskite-type ceramic membrane materials for oxidative coupling of methane ,/ Catal, 164,220-231. 

Olivier L, Haag S, Mirodatos C and van Veen A C (2009), Oxidative coupling of methane using catalyst modified dense perovskite membrane reactors , Catal Today, 142,34-41. 

Tan X, Pang Z, Gu Z and Liu S (2007), Catalytic perovskite hollow fibre membrane reactors for methane oxidative coupling ,/ Afemhrane Sci,3Wl, 109-114. 

Zeng Y, Lin Y S and Swartz S L (1998), Perovskite-type ceramic membrane synthesis, oxygen permeation and membrane reactor performance for oxidative coupling of methane , Membrane Sci, 150,87-98. 

Taheri, Z., Nazari, K., Safekordi, AA., Seyed-Matin, N., Ahmadi, R., Esmaeili, N., and Tofigh, A. (2008) Oxygen permeation and oxidative coupling of methane in membrane reactor a new fecile synthesis method for selective perovskite catalyst. 

Czuprat, O., Schiestel, T., Voss, H., and Caro, J. (2010) Oxidative coupling of methane in a BCFZ perovskite hollow fiber membrane reactor. Ind. Eng. Chem. Res., 49, 10230-10236. 

Zeng, Y., Lin, Y. and Swartz, S. (1998). Perovskite-Type Ceramic Membrane Synthesis, Oxygen Permeation and Membrane Reactor Performance for Oxidative Coupling of Methane, J. Membrane Sci., 150, pp. 87-98. 

Taheri, Z., Nazari, K., Safekordi, A., et al (2008). Oxygen Permeation and Oxidative Coupling of Methane in Membrane Reactor A New Facile Synthesis Method for Selective Perovskite Catalyst, J. Mol Catal A Chem., 286, pp. 79-86. 

Olivier, L., Haag, S., Mirodatos, C., etal. (2009). Oxidative Coupling of Methane Using Catalyst Modified Dense Perovskite Membrane Reactors, Catal. Today, 142, pp. 34-41. 

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