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Pericyclic reactions carbon shift

This reaction does not proceed via a Whitmore 1,2-shift, but instead is a concerted pericyclic [3,3] sigmatropic rearrangement that results in a cyclic ketone, which after tautomerisation, gives the phenol. Furthermore, in this reaction a C-0 bond is broken, rather than made, and a C-C bond is formed thus, it could have been considered under carbon/carbon rearrangements. [Pg.322]


See other pages where Pericyclic reactions carbon shift is mentioned: [Pg.597]    [Pg.13]    [Pg.121]    [Pg.187]    [Pg.597]    [Pg.255]    [Pg.1163]    [Pg.389]    [Pg.776]    [Pg.915]    [Pg.294]    [Pg.1454]    [Pg.1143]    [Pg.74]    [Pg.1677]    [Pg.366]   


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Carbon shift reactions

Pericyclic

Pericyclic reactions

Pericyclic reactions 1.3] -shift

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