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Perchloryl fluoride caution

Flnorination of an ester. Grieco et alf have successfully fluorinated the enolate of the ester (1) with perchloryl fluoride. Caution A violent explosion occurred in one experiment conducted below —40". Two products, (2) and (3), were... [Pg.144]

Metal enolates can be fluorinated successfully with perchloryl fluoride, e. g. formation of 4,114 but due to the aggressive nature of perchloryl fluoride its applications are limited114 (caution see Vol.ElOa, p265ff). Alternatively, fluorination can be performed by acetyl hypofluorite generated from elemental fluorine and acetic acid/sodium acetate,95115 e.g. formation of 2-fluoro-l-phenylethanone (5).115... [Pg.28]

Caution Two laboratories have reported serious explosions in reactions with perchloryl fluoride. [Pg.454]

See other pages where Perchloryl fluoride caution is mentioned: [Pg.30]    [Pg.323]   
See also in sourсe #XX -- [ Pg.14 , Pg.30 ]

See also in sourсe #XX -- [ Pg.14 , Pg.30 ]



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Perchloryl fluoride

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