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PERCHLORYL COMPOUNDS

It proved to be remarkably stable to high temperature (Engelbrecht and Atz-wanger [44]). [Pg.489]

It is not hydrolysed by water but reacts quantitatively with NaOH to yield sodium perchlorate and fluoride. It oxidizes iodides to iodine. Perchloryl fluoride reacts with ammonia to yield ammonium perchlorylamide NH4NHCIO3 [45a]. It reacts with potassium and caesium hydroxide to yield crystalline precipitates of K2NCIO3 and CS2NCIO3. It is isomorphous with metal sulphates, is explosive and very sensitive to flame, shock and friction. [Pg.489]

It is quite safe to handle, but being a powerful oxidizing agent, it reacts violently with any oxidizable substance. [Pg.489]

Details about the safety in handling perchloryl fluoride are described by Pennsalt Chemicals Corp. [45]. [Pg.489]

O-X Alkyl perchlorates. Chlorite salts. Halogen oxides, Hypohalites, Perchloric acid, Perchloryl Compounds... [Pg.237]

AMINIUM PERCHLORATES CHLORITE SALTS HALOGEN OXIDES HYPOHALITES PERCHLORYL COMPOUNDS... [Pg.150]

OXOHALOGEN ACIDS, OXYGEN ENRICHMENT 1 -OXYPEROXY COMPOUNDS, OZONIDES PERCHLORYL COMPOUNDS, PEROXOACIDS PEROXOACID SALTS, PEROXYACIDS PEROXYCARBONATE ESTERS, PEROXYESTERS POLYNITROALKYL COMPOUNDS, POLYPEROXIDES QUATERNARY OXIDANTS, TRINITROETHYL ORTHOESTERS XENON COMPOUNDS... [Pg.307]

The need for great care to avoid the possibility of detonation of perchloryl compounds by exposure to shock, overheating or sparks is stressed. The compounds are generally more sensitive to impact than mercury fulminate and are of comparable sensitivity to lead azide [1], A range of highly explosive alkyl perchlorates [2] and perchlorylamines [3] have been prepared by interaction of dichlorine heptaoxide with alcohols or amines in carbon tetrachloride solution. The solutions of the products were not sensitive to mechanical shock and could... [Pg.325]

Perchlorotriptycene, mass spectrum, 33 20-21 iV-Perchloryl compounds, 19 49-52 infrared spectra, 19 49-52 PerehloiyJ fluoride, 18 371-385 chemical properties, 18 380-384 dipole moment, 18 374 eigenvalues for, 18 377 frequency values, 18 374 ionization data for, 18 376 molecular structure of, 18 373-377 physical properties of, 18 377-380 preparation and reaction, 27 177-178 preparation of, 5 66-68 properties of, 5 68... [Pg.230]

A number of perchloryl compounds were prepared by this method with a good yield. [Pg.489]

This analogue of picric acid is dangerously explosive and very shock-sensitive. See other PERCHLORYL COMPOUNDS, POLYNITROARYL COMPOUNDS... [Pg.766]

PERCHLORYL COMPOUNDS PEROXOACID SALTS PEROXOACIDS PEROX Y ACIDS... [Pg.2504]

See other pages where PERCHLORYL COMPOUNDS is mentioned: [Pg.2313]    [Pg.636]    [Pg.680]    [Pg.696]    [Pg.730]    [Pg.1134]    [Pg.1340]    [Pg.325]    [Pg.325]    [Pg.326]    [Pg.306]    [Pg.306]    [Pg.488]    [Pg.489]    [Pg.721]    [Pg.781]    [Pg.807]    [Pg.1189]    [Pg.1383]    [Pg.2520]    [Pg.2520]    [Pg.2521]    [Pg.2640]    [Pg.636]    [Pg.680]    [Pg.696]    [Pg.730]    [Pg.1134]    [Pg.1340]    [Pg.2068]    [Pg.346]    [Pg.636]    [Pg.696]   
See also in sourсe #XX -- [ Pg.315 ]



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Organic perchloryl compounds

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