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Pentadienoates, nucleophilic additions

Early investigations of additions of soft carbon nucleophiles to simple Michael acceptors like ethyl sorbate date back to the beginning of the 20th century. Already in 1906. Vorlauder and coworkers described additions of malonate anion whereas ethyl sorbate provided the 1,6-addition product (equation 2), the 1,4-adduct was obtained from methyl 5-phenyl-2,4-pentadienoate (equation 3). Thus, it seems that the regioselectivity... [Pg.647]

See other pages where Pentadienoates, nucleophilic additions is mentioned: [Pg.652] [Pg.666] [Pg.652] [Pg.652] [Pg.666]

See also in sourсe #XX -- [ Pg.647 , Pg.648 , Pg.652 , Pg.666 ]

See also in sourсe #XX -- [ Pg.647 , Pg.648 , Pg.652 , Pg.666 ]

See also in sourсe #XX -- [ Pg.647 , Pg.648 , Pg.652 , Pg.666 ]

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2,4-Pentadienoates

Pentadienoates, nucleophilic additions Pentadienyl)Fe 3+ cations