Paramagnetic organometallics

Chatgilialoglu, C. In Paramagnetic Organometallic Species in Activation / Selectivity, Catalysis, M. Chanon, M. Julliard, and J. C. Poite (Eds), Kluwer, Dordrecht, 1989, pp. 119-129. (Proceedings of a NATO ARW held in St. Maximin, France, 4-9 October 1987). 

Electronic Structure of Solids Magnetism of Transition Metal Ions Paramagnetic Organometallic Complexes. 

In other cases, non-chain radical reactions have been suggested see Paramagnetic Organometallic Complexes). 

Bonding Energetics of Organometallic Compounds Electron Transfer in Coordination Compounds Paramagnetic Organometallic Complexes Structure Property Maps for Inorganic Solids. 

Modem transition metal organometallic chemistry can be said to have been invigorated by the discovery and subsequent bonding description of ferrocene (see Ferrocene) by Wilkinson and Fischer in 1951. As predicted by MO theory, all of the neutral first-row metallocenes (see Metallocene Complexes) (V Ni) are paramagnetic, with the exception of ferrocene. Metallocenes probably represent the most studied of all paramagnetic organometallic complexes. 

Reactions and Catalytic Cycles Involving Paramagnetic Organometallic Species... 

D. R. Tyler and A. Avery, Paramagnetic Organometallic Complexes, Encyclopedia of Inorganic Chemistry , Wiley, Chichester, 1994, p. 3055. 

A wide variety of paramagnetic organometallic compounds are known. The large majority of these are classified as metallocenes and are of considerable NMR interest. In studying such systems Kohler (179) has suggested that spectroscopy offers distinct advantages over spectroscopy. From studies on bis-(h -t-butyl-... 

In this chapter and in an upcoming review (Part II), the chemistry of mononuclear paramagnetic organometallic complexes of the second- and third-row groups 9(VIIIB) and lO(VlII) platinum metals (Rh, Ir, Pd, Pt) are summarized. In this chapter, the higher valent species (Rh(II), Ir(II), Rh(IV), Ir(IV), Pd(ni), Pt(III) and complexes with oxidized redox noninnocent ligands) are described. In the next chapter, the lower valent species (Rh(0), lr(0), Pd(I), Pt(I), and complexes with reduced redox noninnocent ligands will be discussed. 

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