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Palladium, organo- compounds reagents

Acylation of organozinc reagents. Reaction of acyl chlorides with organozinc compounds catalyzed by palladium-phosphine complexes provides a general synthesis of ketones. The organozincs are readily available by treatment of the corresponding organo-lithium with ZnCh. Alkenylzinc compounds and a,p-unsaturated acyl chlorides react with retention of the stereochemistry. Isolated yields of ketones are 55-90%. [Pg.471]

See other pages where Palladium, organo- compounds reagents is mentioned: [Pg.3]    [Pg.12]    [Pg.840]    [Pg.58]    [Pg.62]    [Pg.648]    [Pg.727]    [Pg.16]    [Pg.140]    [Pg.471]    [Pg.233]    [Pg.497]    [Pg.116]    [Pg.102]    [Pg.184]   
See also in sourсe #XX -- [ Pg.507 , Pg.508 , Pg.509 ]

See also in sourсe #XX -- [ Pg.507 , Pg.508 , Pg.509 ]



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Palladium, organo- compounds

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