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Palladium complexes Baeyer-Villiger oxidation

In 1998, Strukul and coworkers presented a diphosphine-palladium complex, with which the Baeyer-Villiger oxidation of cyclic and for the first time also acyclic ketones could be catalyzed in the presence of various peroxidic oxidants (H2O2, TBHP, KHSO5, carbamide peroxide) (Scheme 158)4 . pj-om these oxidants H2O2 turned out to be the most efficient one, whereas almost no conversion was obtained (<1% after several days) with TBHP. The authors could show that an increase in the bite angle of the diphosphine caused... [Pg.539]

The asymmetric Baeyer-Villiger oxidation using a palladium complex of 2-(phosphinophenyl)pyridine ligand provides a useful procedure for the synthesis... [Pg.262]

Ito K, Ishii A, Kuroda T, Katsuki T. Asymmetric Baeyer-Villiger oxidation of prochiral cyclobutanones using a chiral cationic palladium(II) 2-(phosphinophenyl)pyridine complex as catalyst. Synlett 2003 643-646. [Pg.1069]

See other pages where Palladium complexes Baeyer-Villiger oxidation is mentioned: [Pg.175]    [Pg.46]    [Pg.245]    [Pg.263]   
See also in sourсe #XX -- [ Pg.227 ]



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