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Packed geometries for

Table I presents the detailed packing geometries for ensembles consisting of up to two independently orientable chains of like conformation. Although analysis by simulation suggests several distinguishable candidates of comparable energy for chain packing in the oriented PPTA solid state, the predominant trends in structure formation may be deduced from the common elements across the set of packed geometries. The... Table I presents the detailed packing geometries for ensembles consisting of up to two independently orientable chains of like conformation. Although analysis by simulation suggests several distinguishable candidates of comparable energy for chain packing in the oriented PPTA solid state, the predominant trends in structure formation may be deduced from the common elements across the set of packed geometries. The...
A theoretical maximnm fibre volnme fraction can be calculated for each packing geometry. For the sqnare array and close packing shown in Fig. 11.14, the maximnm fibre volnme fraction is given as... [Pg.315]

Adamski, RP Anderson, JL, Configurational Effects on Polystyrene Rejection from Micro-porosou Membranes, Journal of Polymer Science Part B Polymer Physics 25, 765, 1987. Adler, PM, Porous Media, Geometry and Transports Butterworth-Heinemann Boston, 1992. Afeyan, NB Fulton, SP Regnier, FE, Perfusion Chromatography Packing Materials for Proteins and Peptides, Journal of Chromatography 544, 267, 1991. [Pg.607]

The difference between the fee and hep structure is best seen if one considers the sequence of dose-packed layers. For fee lattices this is the (111) plane (see Figs. 5.1 and 5.3), for hep lattices the (001) plane. The geometry of the atoms in these planes is exactly the same. Both lattices can now be built up by stacking dose-packed layers on top of each other. If one places the atoms of the third layer directly above those of... [Pg.169]

To create a useful CFD simulation the model geometry needs to be defined and the proper boundary conditions applied. Defining the geometry for a CFD simulation of a packed tube implies being able to specify the exact position and, for nonspherical particles, orientation of every particle in the bed. This is not an easy task. Our experience with different types of experimental approaches has convinced us that they are all too inaccurate for use with CFD models. This leads to the conclusion that the tube packing must either be computergenerated or be highly structured so that the particle positions can be calculated analytically. [Pg.325]

The inclusion of chemical reaction into CFD packed-tube simulations is a relatively new development. Thus far, it has been reported only by groups using LBM approaches however, there is no reason not to expect similar advances from groups using finite volume or finite element CFD methods. The study by Zeiser et al. (2001) also included a simplified geometry for reaction. They simulated the reaction A + B - C on the outer surface of a single square particle on the axis of a 2D channel (Fig. 16). [Pg.355]

Addition of 5% ganglioside Gmi into the L-Glu-Bis-3 resulted in the appearance of vesicles along with twisted ribbons, while addition of nonchiral 10,12-docosadiynedioic acid caused the formation of platelets.97 These results affirm the importance of packing geometry, along with head group chirality, for the formation of helical structures. [Pg.311]

Cubed compound, in PVC siding manufacture, 25 685 Cube lattice, 8 114t Cubic boron nitride, 1 8 4 654 grinding wheels, 1 21 hardness in various scales, l 3t physical properties of, 4 653t Cubic close-packed (CCP) structure, of spinel ferrites, 11 60 Cubic ferrites, 11 55-57 Cubic geometry, for metal coordination numbers, 7 574, 575t. See also Cubic structure Cubic symmetry Cubic silsesquioxanes (CSS), 13 539 Cubic structure, of ferroelectric crystals, 11 94-95, 96 Cubic symmetry, 8 114t Cubitron sol-gel abrasives, 1 7 Cucurbituril inclusion compounds,... [Pg.237]

Even though qualitative bonding descriptions of metal atom clusters up to six or seven atoms can be derived and in some cases correlated with structural detail, it is clear that most structures observed for higher clusters cannot be treated thus. Nor do the structures observed correlate with those observed for borane derivatives with the same number of vertices. Much of borane chemistry is dominated by the tendency to form structures derived from the icosahedron found in elemental boron. However, elemental transition metals possess either a close-packed or body-centered cubic arrangement. In this connection, one can find the vast majority of metal polyhedra in carbonyl cluster compounds within close-packed geometries, particularly hexagonal close-packing. [Pg.248]

Coordination number and packing geometry. On the basis of the previous definition of the coordination number (as the number of first neighbours), and of the corresponding coordination geometries (as listed in Table 3.4) some additional remarks may be useful for the particular case of packing of hard sphere atoms. [Pg.125]


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