P-methoxyphenyl

Photocycloaddition. Synthesis of the highly carcinogenic polycycHc hydrocarbons, eg (51) [72735-91-2] may be affected by photocycloaddition of 2-bromo-3-methoxy naphthoquinone [26037-61-6] with 1,1-diarylethylenes such as l,l-bis(p-methoxyphenyl)ethene (41). 

Dlmethyl-3-carboxyethyl-5 p-methoxyphenyl)-4,5 dlhydrofuran (3).3 A mixture of syn and anti cyclopropyl-p ketoesters 1 and 2 was left in contact with neutral akjmina activity I in CHCI3 for 24 h The starting materials 1 and 2 disappeared and 3, homogeneous by HPLC and NMR in quantitative yield, was isolated... 

It is possible to introduce this group selectively onto a primary alcohol in the presence of a secondary alcohol. The derivative is stable to KMn04, w-chloro-peroxybenzoic acid, LiAlH4, and Cr03 Pyr. Since this derivative is similar to the p-methoxyphenyl ether it should also be possible to remove it oxidatively. The GUM ethers are less stable than the MEM ethers in acid but have stability comparable to that of tlie SEM ethers. It is possible to remove the GUM ether in the presence of a MEM ether. 

THE C-ARYLATION OF g-DICARBONYL COMPOUNDS ETHYL l-(p-METHOXYPHENYL)-2-OXOCYCLOHEXANECARBOXYLATE... 

B. Ethyl l-( p-methoxyphenyl I-2-oxoayotohexaneaar hoxylate. A 250 mL, one-necked, round-bottomed flask, equipped with a magnetic stirring bar, is charged with 22.2 g (45 mmol) of p-methoxyphenyl 1 ead triacetate, 10.8 g (135 mmol) of pyridine (Note 8), and 70 mL of chloroform (Note 9). To this solution 1s added 7.0 g (41 mmol) of ethyl 2-oxocyclohexanecarboxylate (Note 10), a calcium chloride drying tube Is put 1n place, and the mixture is stirred at 40°C (Note 11). 

Bis(4-methoxyphenyl)-l,3,2,4-d1thiadiphosphetane 2,4-disulfide Phos-phonotrithiolc acid, (p-methoxyphenyl)-bimol cyclic anhydrosuifide (8) ... 

Chemical Designations - Synonym 2,2-Bis(p-methoxyphenyl)-l,l,l-trichloroethane 2,2-Di-(p-anisyl)-l,l,l-trichloroethane DMDT Marlate50 Methoxy-DDT Chemical Formula Cj HijCljOj. 

The stabilized fluorinated allylic cation, generated from cis- or trans-l-(p-methoxyphenyl)pentafluoropropene and antimony pentafluoride in sulfur dioxide, is solvolyzed by methanol to methyl 2-(p-methoxyphenyl)difluoroacrylate [36] (equation 37)... 

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