Oxytelluration alkenes

Electrophilic addition reactions of tetravalent tellurium compounds have been reviewed.64 2-Naph-thyltellurium trichloride (ArTeCb) adds to alkenes in an anti stereospecific manner (equation 11), whereas tellurium tetrachloride gives mixtures of 2 1 adducts with both syn and anti addition.72 A one-pot alkene inversion procedure has been developed, based upon TeCU addition to alkenes followed by treatment of the (3-chloroalkyltellurium trichloride adduct with aqueous Na2S (Scheme 37).73 Tellurium compounds such as tellurinyl acetates, ArTe(0)0Ac, prepared in situ through reaction of tellurinic acid anhydrides with acetic acid, can be employed in oxytelluration and aminotelluration procedures (Schemes 38 and 39).74 In the oxytelluration reaction intermediate triacetates of the type RCH2Te(OAc)2Ph are reduced with hydrazine to the corresponding tellurides. 

Oxytelluration of terminal alkenes followed by elimination of the tellurium moiety gives enol ethers as shown in Scheme 7. ... 

---

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

---