Oxymercuration and related Reactions

Peroxymercuration was again a popular area of study among the reactions looked at were (i) formation of cyclic peroxides, O—CH(CHaH 0(CH8) [Pg.27]

Use of a partially aqueous media renders aminomercuration, e.g. of CHa==CHa by PhNHR and Hg(OAc)a, an easy reaction. Mercury derivatives of hetero-cyclics are formed from (H20=CHCH2)2Y (Y = O, S, or NH), HaNAr, and Hg(0Ac)a in THF. [Pg.27]

Symmetrization of ROCHgCHaKgOAc has been readily achieved using SnCla-NaOH. [Pg.27]

Methylmercury Compounds.— The mechanism of methylation of HgCla by methyl-cobalamin (30) involves transfer of a methyl carbanion from base on (30). Electrochemical formation of McaHg was reported using a Hg anode in a NaCl,MeAlCla melt. [Pg.27]

and Raman intensities of the stretching vibrations of MegHg and MeHgX compounds in solution and a review of force constant calculations for MeHgX have been published. [Pg.28]

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