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Oxygen thiolate complexes

Figure 9-39. Sometimes the oxidation of thiolate complexes results in the formation of disulfide complexes rather than oxygen transfer products. Figure 9-39. Sometimes the oxidation of thiolate complexes results in the formation of disulfide complexes rather than oxygen transfer products.
A more common reaction involves oxidation of a coordinated thiolate to disulfide or an S—O compound. The former reaction may occur with or without the involvement of an oxygen transfer reagent (or dioxygen) while the latter requires such a species. The oxidation of the thiolate complex (42) by dioxygen shown in Eq. (9) is first order in (42) and dioxygen, and it is proposed that the sulfenate (43) arises by attack of a noncoordinated thiolate on coordinated dioxygen. ... [Pg.292]

Two thiolate complexes involved in oxygen atom transfer reactions. [Pg.197]

Lee CM, Hsieh CH, Dutta A, Lee GH, Liaw WF. 2003. Oxygen binding to sulfur in nitrosylated iron—thiolate complexes relevance to the Fe-containing nitrile hydratases. JAm Chem Soc 125(38) 11492-11493. [Pg.268]

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See also in sourсe #XX -- [ Pg.108 ]



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Oxygen complexes

Thiolate

Thiolate complexes

Thiolates

Thiolation

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