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Oxygen-, Sulphur-, and Selenium-bonded Compounds

The joint action of tris(dimethylamino)phosphine and carbon tetrachloride on vicinal diols furnished either oxirans or spirophosphoranes 3-0-benzyl-1,2-0-isopropylidene-a-D-gluco- and -allo-furanose, for example, yielded [Pg.121]

The reaction of dibutyltin oxide with pyranoid m-l,2-diols has attracted interest, since the resulting cyclic dibutylstannylene derivatives are substituted regioselectively at the equatorial oxygen-atom when treated with an acyl chloride or an active alkyl halide. Thus the cyclic dibutylstannylene derivative (332  [Pg.122]

R = Bn R = CH2CH=CH2) reacted with benzyl bromide in DMF to give a 66% yield of benzyl 6-0-allyl-2,3-di-0-benzyl-a-D-galactopyranoside (333), and 3-O-substituted derivatives were also formed regioselectively when the structural isomer (332 R = CH2CH=CHa R = Bn) was treated with allyl bromide, benzoyl chloride, or methyl iodide in an aprotic medium. Benzylation [Pg.122]

6-anhydro-/S-D-hexopyranoses were also examined in detail. The approximate location of the cation in the complexes was determined and an attempt was made to explain the shifts in terms of contact and pseudocontact interactions. [Pg.124]

The usefulness of osmium derivatives in nucleic acid chemistry has prompted an investigation of the synthesis and reactions of osmium ligand complexes [e.g. (334)—(336)] of common nucleosides. Such dipyridylosmium esters underwent relatively rapid transesterification reactions with glycols. Other groups have reported n.m.r. studies on the complexes formed between nucleosides and transition-metal carbonyls e.g, [Rh(COa)Cl]2 and W(CO)e and on the ionic binding of Li+ and Cl ions to nucleosides (based on Li and C1 nuclear magnetic relaxation times).  [Pg.124]


See other pages where Oxygen-, Sulphur-, and Selenium-bonded Compounds is mentioned: [Pg.121]   


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Compounds oxygenated

Oxygen and sulphur

Oxygen compounds

Oxygen sulphur

Oxygen, Sulphur, and Selenium

Oxygen-bonded Compounds

Oxygenate compounds

Oxygenous compound

Selenium and compounds

Selenium compounds

Selenium-Oxygen Compounds

Selenium—oxygen bonds

Sulphur and Selenium

Sulphur bonding

Sulphur compounds

Sulphur-Oxygen Compounds

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