Oxygen reduction reaction performance

Mani P, Srivastava R, Strasser P. Dealloyed binary PtM3 (M = Cu, Co, Ni) and ternary PtNbM (M = Cu, Co, Fe, Cr) electrocatalysts for the oxygen reduction reaction performance in polymer electrolyte membrane fuel cells. J Power Sources. 2011 196 666-73. 

The impedance polarization performance of LSM electrode is closely related to the mechanism and kinetics of the oxygen reduction reactions. 02 reduction at SOFC cathodes is the most heavily studied subject, and this subject is sufficiently broad and complex to warrant its own review. Interested readers should consult the recent excellent articles by Adler [1] and Fleig [55], Here, only the polarization performance and its influencing factors are discussed. 

One way to illustrate the effect of the EDL is to compare in situ electrochemical reactions with their equivalent UHV counterparts. Due to their roles in fuel cells, the methanol oxidation reaction and the oxygen reduction reaction are two such reactions for which numerous in situ and UHV experiments have been performed. 

Eligh performance liquid chromatography Density functional theory Oxygen reduction reaction Rotating disk electrode Rotating ring disk electrode... 

If a reaction path is predominant and one of its elementary step is rate determining, the Tafel slope will be characteristic of this step. Thus, electrochemical measurements performed on rotating disk electrode can provide a first solution to elucidate the mechanistic behavior of oxygen reduction reaction on a catalyst. Par-sons has demonstrated that, in a several step electrode process,... 

The primary challenge in commercialization of MCFC remains in the proper selection of materials for the cathode. The life expectancy of the electrode structure is aimed toward 40,000 hr for successful commercialization of MCFC. The following cathode properties were recognized as of fundamental importance with respect to the cell performance 1) high electronic conductivity at 650°C (cr > 1 S/cm) 2) low chemical reactivity and solubility in the electrolyte 3) thermodynamic stability at 650°C in carbonate electrolyte at different partial pressures of O2/CO2 mixtures 4) high electrocatalytic activity for the oxygen reduction reaction and 5) suitability for the fabrication of porous electrodes. ... 

Test benchmark catalysts with half-cell rapid screening technique for their activity in the oxygen reduction reaction (ORR) and compare ranking of catalysts with their performance in polymer electrolyte membrane MEAs. 

We have already shown here that large surface areas translate into enhanced electrochemical performance and, from this perspective, nanostructures are also very important for fuel cell devices [8,70,88-90], particularly as regards the catalyst part of the cell where the oxygen reduction reaction can only occur in spatially confined regions [8,70,88-90]. 

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