Oximes metal complexes

Bacteriochlorins, 851 Barbituric acid metal complexes, 798 Barium alkoxides synthesis, 336 Barium complexes phthalocyanines, 863 porphyrins, 820 Becium homblei copper accumulation, 964 Benzaldehyde, 2-amino-self-condensation aza macrocycles from, 900 Benzamide, o-mercapto-metal complexes, 655 Benzamide oximes metal complexes, 274 Benzamidine, /V, V -diphenyl-metal complexes. 275 Benzene, 1,2-diamino-reactions with dicarbonyl compounds aza macrocycles from, 902 Benzene, 4 methylthionitroso-metal complexes, 804 Benzenedithiolates metal complexes, 605... 

Oxime metal complexes may show pH-dependent redox potentials as indicated in Equation (18). Chakravorty extensively investigated the redox reactions of nickel(II) and iron(II) complexes of linear hexadentate ligands with terminal oxime groups, with the majority of this work focusing on the complex [Ni"(Me2LH2)] shown in Figure At pH < 5, a single reversible wave is... 

Structural chemistrv of transition metal complexes of oximes. A. Chakravorty, Coord. Chem. Rev., 1974,13,1-46 (298). 

Hydrolysis of oximes catalyzed by transition-metal complexes has not been studied prior to a report by Kostic et al. They have reported kinetics of hydrolysis of acetoxime to acetone catalyzed by two palladium(II) complexes, identified active species in the hydrolysis reaction, proposed a reaction mechanism, and fully characterized a bis(acetoxime) complex that is relatively stable toward hydrolysis.458... 

Isatin-3-oximes readily form complexes with a variety of metal ions.278,279 In a number of cases, these have seen analytical applications.6,42,280-283 Isatin-2-oximes1 also form metal complexes.279,284-287... 

Transition metal hydroxyoxime complexes have been reviewed very recently.2507 Their use in both analytical chemistry and extraction metallurgy is well known. The square planar structure of the bis chelate complex NiL (347) with the deprotonated 2-hydroxybenzaldoxime (HL) is typical of this series of nickel complexes.2508 Their bis adducts, NiLJ, with bases such as py, substituted pyridines and cyclomethyleneimines, are six-coordinate.2509 The acyl oxime (H2L) complexes are similar to the aforementioned complexes being either square planar bis chelates Ni(HL)2 (348) or octahedral bis adducts, Ni(HL)2B2.2507 When the acyl oxime acts as a dibasic ligand L, the corresponding (NiL) complexes are insoluble and involve extensive polymerization. 

Cyclodextrins classification, 920 Cyclohexane-1,2-diamine metal complexes, 34 C.yclohexanc-l,2-dione monooxime metal complexes, 273 Cyclohexane-1,3,5-triamine metal complexes, 50 Cyclohexanone oxime... 

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