Oxidizing agents perchloryl fluoride

The perchloryl fluoride [7616-94-6] FCIO, the acyl fluoride of perchloric acid, is a stable compound. Normally a gas having a melting poiat of —147.7° C and a boiling poiat of —46.7°C, it can be prepared by electrolysis of a saturated solution of sodium perchlorate ia anhydrous hydrofluoric acid. Some of its uses are as an effective fluorinating agent, as an oxidant ia rocket fuels, and as a gaseous dielectric for transformers (69). 

These compounds are not stable in aqueous media, each hydrolyzing to the parent acid and the appropriate hydrogen halide. There are two exceptions the first is NO2CI which hydrolyzes in a different manner (p, 245). The second, and more important, is perchloryl fluoride, C103F, which, under the usual laboratory conditions, is inert to moisture. This remarkable substance, which did not exist a decade ago, is now prepared in ton quantities it is an extremely powerful oxidizing agent at high temperature and has become important in propulsion. It is prepared by the reaction of perchlorates with fluorosulfonic acid ... 

Perchloryl fluoride, FClO, is a powerful oxidizing agent and should be handled accordingly. 

MONOPHENYLHYDRAZINE (100-63-0) A highly reactive reducing agent. Combustible solid (flash point 190°F/88°C). Dust or powder forms explosive mixture with air. Reacts violently with oxidizers calcium hypochlorite, fluorine, hydrogen peroxide, perchlorates methyl iodide, 2-phenylamino-3-phenyloxazirane, 3-(3-cyano-l,2,4-oxadiazol-5-yl)-4-cyanofurazan-2-(5-) oxide, dicyanofurazan, dicyanofurazan-n-oxide, lead dioxide. Mixture with perchloryl fluoride forms an explosive material. Incompatible with oxides of iron. 

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