Oxidation with trioxygen ozone

CjF reacts with an excess of trioxygen at room temperature to give COFj and Oj. The formation of an intermediate and unstable ozonide, CjF Oj, was assumed, although CjF O or CF3CFO were not detected. The rates of reaction of C F with O3 are fast, and increase with increase of C F and O3 concentrations. However, at large concentrations of O3, the reaction rate begins to decrease again, probably as a result of diffusion control [923]. [Pg.582]

When a mixture of CjF, and NO in a large excess of argon was heated to 2600 K by reflected shock waves, COFj was formed as a result of the following reactions [1418] [Pg.582]

Because of the high dinitrogen content of the product mixture, the last reaction is considered to be the most important. [Pg.582]

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