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Oxidation of Secondary and Primary Amines

The oxidation of secondary amines to imines can be carried out by hydrogen transfer reaction under mild conditions using a catalytic amount of 9/2,6-dimethoxy benzo-quinone/Mn02 (Eq. 3.30) [65]. [Pg.64]

James et al. reported that aerobic oxidation of primary amines in the presence of a ruthenium porphyrin complex Ru(TMP)(0)2 (TMP = tetramesitylporphyrinato) gives nitriles (100%) (Eq. 3.31) [66]. [Pg.64]

Heterogeneous catalysts such as hydroxyapatite-bound Ru complex [67] and Ru/ AI2O3 [68] can be also used for the aerobic oxidation of primary amines to nitriles (Eqs. 3.32 and 3.33). [Pg.64]

See other pages where Oxidation of Secondary and Primary Amines is mentioned: [Pg.64]    [Pg.667]   


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Amination primary

Amination secondary

Amines primary

Amines primary and secondary

Amines secondary

Oxidation of primary amines

Oxidation of primary amines and

Oxidation of secondary amines

Primary amine, oxidation

Primary and secondary

Primary oxidation

Primary secondary amine

Secondary amines, oxidation

Secondary oxidants

Secondary oxidation

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