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Oxidation chemo-enzymatic methods

A similar oxidative protocol has been used for the oxidation of (fluoroalkyl)alkanols, Rf(CH2) CH20H, to the respective aldehydes [146], in the one-pot selective oxidation/olefination of primary alcohols using the PhI(OAc)2-TEMPO system and stabilized phosphorus ylides [147] and in the chemo-enzymatic oxidation-hydrocyanation of 7,8-unsaturated alcohols [148]. Other [bis(acyloxy)iodo]arenes can be used instead of PhI(OAc)2 in the TEMPO-catalyzed oxidations, in particular the recyclable monomeric and the polymer-supported hypervalent iodine reagents (Chapter 5). Further modifications of this method include the use of polymer-supported TEMPO [151], fluorous-tagged TEMPO [152,153], ion-supported TEMPO [154] and TEMPO immobilized on silica [148],... [Pg.166]

See other pages where Oxidation chemo-enzymatic methods is mentioned: [Pg.705]    [Pg.737]    [Pg.741]    [Pg.64]    [Pg.743]    [Pg.196]    [Pg.344]    [Pg.579]    [Pg.411]    [Pg.567]    [Pg.348]    [Pg.291]   
See also in sourсe #XX -- [ Pg.737 , Pg.741 , Pg.742 , Pg.743 ]



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Enzymatic methods

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