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Oxidant environmentally friendly terminal

Environmentally Friendly Terminal Oxidants 7 TaUel.1 Asymmetric dihydroxylation of different alkenes using NaOCI as the terminal oxidant.. ... [Pg.7]

Obviously there is a definite need in the fine chemical and pharmaceutical industry for catalytic systems that are green and scalable and have broad utihty [10]. More recently, oxidations with the inexpensive household bleach (NaOCl) catalyzed by stable nitroxyl radicals, such as TEMPO [17] and PIPO [18], have emerged as more environmentally friendly methods. It is worth noting at this juncture that greenness is a relative description and there are many shades of green. Although the use of NaOCl as the terminal oxidant affords NaCl as the by-product and may lead to the formation of chlorinated impurities, it constitutes a dramatic improvement compared to the use of chromium(VI) and other... [Pg.9]

See other pages where Oxidant environmentally friendly terminal is mentioned: [Pg.3]    [Pg.3]    [Pg.5]    [Pg.9]    [Pg.11]    [Pg.15]    [Pg.2]    [Pg.3]    [Pg.5]    [Pg.7]    [Pg.9]    [Pg.11]    [Pg.186]    [Pg.233]    [Pg.595]    [Pg.297]    [Pg.292]    [Pg.86]    [Pg.205]    [Pg.410]    [Pg.414]    [Pg.188]    [Pg.174]    [Pg.37]    [Pg.21]   
See also in sourсe #XX -- [ Pg.3 ]



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