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Ring opening oxazoline

In another example, treatment of an oxazoline ester with TMSCl in THF at reflux leads to oxazoline ring opening and furnishes the corresponding 8-chloro-ainino ester in quantitative yield (eq 52). Treatment with TMSBr and TMSI at rt affords the corresponding /3-halo-amino esters in quantitative yield. [Pg.113]

Reductive zj -oxazoline ring opening a-Acylaminocarboxylic acid esters... [Pg.321]

The substrate monomer was synthesized via conventional chemical methods [96]. During enzymatic reaction, three kinds of reactions are possible polymerization of the monomer to synthetic HA, enzymatic and nonen-zymatic hydrolysis of the monomer via the oxazoline ring opening, leading to the GlcA (l 3)GlcNAc disaccharide (Scheme 26). [Pg.197]

Elaboration of (19) involved conversion to an oxazoline, ring-opening and chlorination at the 4-position followed by reduction to eventually give the benzyl ester of 3-ANA benzyl ether. Subsequent acylation and deprotection led to nocardicin A. [Pg.7]

Without additional reagents 2-Oxazoline ring opening Glycosamimides Change in configuration... [Pg.47]


See other pages where Ring opening oxazoline is mentioned: [Pg.293]    [Pg.45]    [Pg.12]    [Pg.16]    [Pg.52]    [Pg.123]    [Pg.169]    [Pg.47]    [Pg.343]    [Pg.33]    [Pg.223]    [Pg.223]    [Pg.225]    [Pg.310]    [Pg.22]    [Pg.199]    [Pg.49]    [Pg.348]    [Pg.478]    [Pg.325]    [Pg.40]    [Pg.61]    [Pg.48]    [Pg.72]    [Pg.193]    [Pg.321]    [Pg.422]    [Pg.422]    [Pg.23]    [Pg.137]    [Pg.237]    [Pg.412]    [Pg.199]    [Pg.85]   
See also in sourсe #XX -- [ Pg.17 , Pg.184 ]

See also in sourсe #XX -- [ Pg.17 , Pg.184 ]

See also in sourсe #XX -- [ Pg.61 ]




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2-Oxazoline-5-ones ring opening reactions

2-oxazoline ring

3- Oxazolin-5-ones, 2-arylidene derivatives ring-opening

Oxazolines ring opening

Oxazolines ring opening

Ring-Opening Polymerization of Oxazolines

Ring-opening polymerizations 2-oxazolines

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