Oxaziranes estimation

The most characteristic property of the oxaziranes is tlieir strong oxidizing character which is approximately equal to that of hydrogen peroxide. Oxaziranes react with hydrochloric acid the chlorine thus liberated is, however, used up in secondary reactions. " Two equivalents of iodine are formed from acid iodide solutions according to Eq. Titration of the free iodine allows a simple estimation of... 

The almost quantitative formation of free ammonia can be used for an estimation of the oxazirane. With pure oxaziranes, ammonia yields of 93-96% are obtained. 

---

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

---