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Other Related Complexes with Chiral-at-Metal Centre

3 Other Related Complexes with Chiral-at-Metal Centre [Pg.71]

Several chiral complexes were prepared with a variety of transition metals. For example the iron complex CpFe(CO)(COR)(PPh3) (3.11) was prepared and resolved. Such a complex is configurationally stable, and its application to stoichiometric [Pg.71]

2 Half-sandwich Complexes with Chiral Cp Equivalents [Pg.72]

Another method that allows enantioselective synthesis of half-sandwich complexes with a chiral metal centre is to replace the hgand with a chiral Cp- equivalent. Such [Pg.72]




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