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Other non-metal halides

Reaction of [Nba2Cp2] with SbFs in liquid SQ2 yields the oxidation product, [Nb02Cp2][SbF6l and SbF3.i59 in the same report, oxidation of [VQ2Cp2]by AsFs with the formation of YQ2Cp2][AsF6] was described. [Pg.259]

Oxaljd chloride and oxal)d bromide are also non-traditional oxidants that have teen usefully employed in inorganic and coordination diemistry. It has teen estaldished that (COCD2, in the gas phase, can oxidize many transition metals including the platinum group metals ruthenium, rhodium, iridium and platinum. In particular, co-condensation of rhodium or platinum with oxal chloride lea to formation of [Rh(p-Q)(CO)2h and c/s-[PtQ2(CO)2l respectively. [Pg.259]

In this reaction phosgene can be used as an oxidant instead of oxal)i diloride. [Pg.259]

Organic 1,2-dihalides can oxidize certain metals. For example, the slow addition of samarium or ytterbium to a solution of 1,2-diiodoethane in THF leads to the formation of Sml2 and YW2 in quantitative yields, gq. 8.48  [Pg.259]

The reaction is rapid at room temperature. Karrakerl has reported the interaction of metallic plutonium widt a solution of diiodoethane in THF. [Pg.259]


See other glass incidents See other non-metal halides... [Pg.67]

See alkyl nitrates Lewis acids See Other NON-METAL HALIDES... [Pg.69]

See Sodium Non-metal halides (reference 8) See other NON-METAL halides... [Pg.1525]

See other NON-METAL HALIDES, oxidants, xenon compounds... [Pg.1537]

Krypton difluoride, 4313 Potassium hexaoxoxenonate-xenon trioxide, 4674 Tetrafluoroammonium hexafluoroxenate, 4386 Xenon difluoride dioxide, 4322 Xenon difluoride oxide, 4319 Xenon difluoride, 4332 Xenon hexafluoride, 4377 Xenon tetrafluoride, 4353 Xenon tetrafluoride oxide, 4346 Xenon tetraoxide, 4863 Xenon trioxide, 4857 Xenon(II) fluoride methanesulfonate, 0443 Xenon(II) fluoride perchlorate, 3977 Xenon(II) fluoride trifluoroacetate, 0634 Xenon(II) fluoride trifluoromethanesulfonate, 0356 Xenon(IV) hydroxide, 4533 Xenon(II) pentafluoroorthoselenate, 4382 Xenon(II) pentafluoroorthotellurate, 4383 Xenon(II) perchlorate, 4110 See Other NON-METAL HALIDES, NON-METAL OXIDES... [Pg.419]

Interaction with warm water is very rapid and may be violent with limited quantities. See other NON-METAL HALIDES... [Pg.131]


See other pages where Other non-metal halides is mentioned: [Pg.59]    [Pg.59]    [Pg.66]    [Pg.68]    [Pg.119]    [Pg.120]    [Pg.123]    [Pg.124]    [Pg.1341]    [Pg.1346]    [Pg.1434]    [Pg.1440]    [Pg.1442]    [Pg.1454]    [Pg.1461]    [Pg.1463]    [Pg.1467]    [Pg.1510]    [Pg.1522]    [Pg.1525]    [Pg.1526]    [Pg.1530]    [Pg.1532]    [Pg.1537]    [Pg.1537]    [Pg.1543]    [Pg.1545]    [Pg.57]    [Pg.69]    [Pg.87]    [Pg.125]   


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Non-metallics

Non-metals

Other Metal Halides

Other metals

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