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Osmium complexes phosphorus donors

Table VI lists the known trifluoroacetato complexes of iron, ruthenium, and osmium. Photochemical substitution reactions of various tricovalent phosphorus-donor ligands with (7r-allyl)Fe(C0)2(02CCF3) and (iT-Cp)Fe(C0)3(02CCF3), analogous to those described in the preceding for Mn(C0)5(02CCF3), have afforded (ir-allyl)Fe(CO)(cis-Ph2PCH=CHPPh2)(02CCF3), (7r-Cp)Fe(C0)(PR3)(02CCF3) (where... Table VI lists the known trifluoroacetato complexes of iron, ruthenium, and osmium. Photochemical substitution reactions of various tricovalent phosphorus-donor ligands with (7r-allyl)Fe(C0)2(02CCF3) and (iT-Cp)Fe(C0)3(02CCF3), analogous to those described in the preceding for Mn(C0)5(02CCF3), have afforded (ir-allyl)Fe(CO)(cis-Ph2PCH=CHPPh2)(02CCF3), (7r-Cp)Fe(C0)(PR3)(02CCF3) (where...
Two significant surveys are published in the sane edition of Coordination Chemistry Reviews. Oxygen donor-ligand derivatives of tri-osmium dodecacarbonyl are covered by Frauenhoff and the reactions of transition metal dihydrogen complexes (of which many are carbonyl-containing) are outlined by Jessop and Morris. The crucial role of matrix Isolation studies is well covered in this article. A shorter review of interest here has been published on the role of the phosphorus d-orbitals in M-P bonding. ... [Pg.144]

See other pages where Osmium complexes phosphorus donors is mentioned: [Pg.301]    [Pg.292]    [Pg.54]    [Pg.668]    [Pg.863]    [Pg.78]    [Pg.122]    [Pg.93]    [Pg.768]    [Pg.202]    [Pg.529]   
See also in sourсe #XX -- [ Pg.57 , Pg.58 , Pg.64 ]

See also in sourсe #XX -- [ Pg.57 , Pg.58 , Pg.64 ]

See also in sourсe #XX -- [ Pg.57 , Pg.58 , Pg.64 ]

See also in sourсe #XX -- [ Pg.57 , Pg.58 , Pg.64 ]



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