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Osmium carbonyl clusters bonding

Platinum nanoparticles, preparation, 12, 78 Platinum-nitrogen bonds, in platinacycles, 8, 508 Platinum-osmium carbonyl clusters, characteristics, 8, 420 Platinum-oxygen bonds, in platinacycles, 8, 505 Platinum particles, surface reactivity, 12, 542 Platinum-phosphorus bonds, in platinacycles, 8, 508 Platinum-rhenium carbonyl clusters, characteristics, 8, 420 Platinum(II)-ruthenium(II) binary complexes, preparation,... [Pg.173]

Osmium forms stronger metal-metal bonds than either iron or ruthenium consequently, there are a large number of osmium carbonyl clusters see Cluster) and these complexes have a large body of reaction chemistry. The triosmium cluster are prepared from Os3(CO)i2. Most are diamagnetic... [Pg.3375]

Figure 4.16. Plot of metal-metal bond energy per metal atom against valence shell electron numbers per metal atom for osmium carbonyl clusters [OSx(CO)y] " and [Os (CO)yH,]-... Figure 4.16. Plot of metal-metal bond energy per metal atom against valence shell electron numbers per metal atom for osmium carbonyl clusters [OSx(CO)y] " and [Os (CO)yH,]-...
In 1977 we reported a method based on graph theory for study of the skeletal bonding topology in polyhedral boranes, carboranes, and metal clusters Q). Subsequent work has shown this method to be very effective In relating electron count to cluster shape for diverse metal clusters using a minimum of computation. Discrete metal clusters treated effectively by this method Include post-transition metal clusters (, ) > osmium carbonyl clusters (O, gold clusters, platinum carbonyl clusters (J., 7 ) > and... [Pg.54]

R.D. Adams, I.T. Horvath - The Unusual Structures, Bonding, and Reactivity of Some Sulfido-Bridged Tungsten-Osmium Carbonyl Cluster Compounds,... [Pg.582]


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See also in sourсe #XX -- [ Pg.236 ]

See also in sourсe #XX -- [ Pg.236 ]




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Osmium carbonyl clusters

Osmium clusters

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