Organozinc halides structure

Although the simple alkylzinc halides RZnX (R = Me or Et, X = Cl, Br, I) were among the first known organozinc compounds, for a long time nothing was known about the actual structures of such compounds in solution or in the solid state. The constitution of these compounds in solution seemed to depend on the particular solvent employed " . It should be noted that in ethereal solutions, the possibility of the presence of a Schlenk equilibrium should always be considered. In these solvents the organozinc halides most... 

Despite the extensive history of organozinc chemistry, the first solid-state structure of a Lewis base-free diorganozinc compound with cr-bound ligands, namely diphenylzinc, was not reported until 1990.37 Diphenylzinc was synthesized by the transmetallation of diphenylmercury with metallic zinc (Scheme 10) and, after multiple sublimations, obtained halide free in 67% yield. 

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