Organotin Compounds with Cobalt Rhodium and Iridium

7 ORGANOTIN COMPOUNDS WITH COBALT RHODIUM AND IRIDIUM 

The organic derivatives containing a direct tin metal bond listed in Table 260 are prepared by the following methods. 

II Addition of triorganotin hydride or deuteride to (RPh3P)aIrC0X. 

By rxn. of MesSnCl in N atm. with NaCo(C0)4 in anhyd. EtaO, in 95 yield (730), with 003(00)3 in MeOH (I672). 

Listing of organotin derivatives containing cobalt, rhodium and iridium concludes in Table 260. Other bimetallic and polymetallic organotin-cobalt compounds are summarized in Ohapters. 5 6.1 and 6.6, respectively. 

---