Organosulfur ligands

Bidentate organosulfur ligands have been synthesized in a similar manner to the simple organosulfur compounds, e.g. equation (68). 

The aryl group in the same organosulfur ligand as well as in methyl naphthyl sulfide and 2-biphenyl methyl sulfide can be metallated by palla-... 

Alkylation reactions which induce rearrangements or lead to further reactions of the organosulfur ligands are our concern here. Once again, reactions involving thiocarbonyl, dithiocarbene, and CS2 complexes are not discussed since they have been reviewed (3-5). 

According to the present classification, the addition of PMe2Ph to [Os3(CO) o(/ -SCH2CH=CH2)( = H)] (569) which induces formal insertion of the organosulfur ligand into the metal hydride bond to form 612,... 

The evidence reviewed above suggests that cystine, cysteine, mercaptocarboxylic acids, and other organosulfur ligands may contribute to the speciation of metals and sulfur in ore-forming processes responsible for syngenetic deposition of metal sulfides in low-temperature subaqueous... 

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