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Organolithiums reaction with acetone

The orientation of the entering nucleophile in the Emmert reaction304,305 presents features which differ from those observed in the reactions of organolithium compounds with pyridines, and deserves further study. When pyridine is heated with acetone in the presence of magnesium and mercuric chloride, 2-pyridyldimethyl-carbinol (127, R = H) is obtained. Unfortunately, the yields in this... [Pg.300]

See other pages where Organolithiums reaction with acetone is mentioned: [Pg.308]    [Pg.337]    [Pg.673]    [Pg.820]    [Pg.182]    [Pg.198]    [Pg.192]    [Pg.195]    [Pg.150]    [Pg.376]    [Pg.603]    [Pg.83]    [Pg.313]    [Pg.107]    [Pg.1434]    [Pg.214]    [Pg.339]   


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Acetone reactions

Acetone, reactions with

Organolithium reaction

Reaction with organolithium

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