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Organolithium reagents, reaction with conjugated carbonyls

The chemical behavior of heteroatom-substituted vinylcarbene complexes is similar to that of a,(3-unsaturated carbonyl compounds (Figure 2.17) [206]. It is possible to perform Michael additions [217,230], 1,4-addition of cuprates [151], additions of nucleophilic radicals [231], 1,3-dipolar cycloadditions [232,233], inter-[234-241] or intramolecular [220,242] Diels-Alder reactions, as well as Simmons-Smith- [243], sulfur ylide- [244] or diazomethane-mediated [151] cyclopropanati-ons of the vinylcarbene C-C double bond. The treatment of arylcarbene complexes with organolithium reagents ean lead via conjugate addition to substituted 1,4-cyclohexadien-6-ylidene complexes [245]. [Pg.36]

Sulphoximine ylides also have been prepared using organolithium reagents as the base, but the presence of the lithium cation changes the course of the reaction with carbonyl compounds and with conjugated... [Pg.332]

See other pages where Organolithium reagents, reaction with conjugated carbonyls is mentioned: [Pg.1302]    [Pg.728]    [Pg.471]    [Pg.902]    [Pg.115]    [Pg.169]    [Pg.350]    [Pg.728]    [Pg.285]    [Pg.1301]    [Pg.1554]    [Pg.82]    [Pg.789]    [Pg.809]    [Pg.728]    [Pg.789]    [Pg.626]    [Pg.315]    [Pg.174]    [Pg.99]    [Pg.502]    [Pg.247]    [Pg.125]    [Pg.591]    [Pg.101]    [Pg.754]    [Pg.113]    [Pg.59]    [Pg.649]    [Pg.1336]    [Pg.754]    [Pg.304]    [Pg.754]    [Pg.233]    [Pg.354]    [Pg.233]    [Pg.354]    [Pg.298]    [Pg.362]   
See also in sourсe #XX -- [ Pg.615 ]



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Carbonyl reagent

Conjugate reaction

Conjugated carbonyls

Conjugated reaction

Conjugation, reagents

Conjugative reactions

Organolithium reaction

Organolithium reagents

Organolithium reagents reaction

Organolithiums reagents

Reaction with organolithium

Reaction with organolithium reagents

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