Quantitative analysis organolithium compounds

SN2 reactions of primary organolithium compounds on PMMA in dilute homogeneous solution may be considered as a model system where all the important reaction parameters may be controlled they allow both a quantitative analysis of PMMA chain reactivity and the synthesis of well defined ketonic copolymers within a wide range of possible structural variations. The two homologous series of organolithium compounds and the corresponding reaction conditions we selected are given below ... 

The quantitative analytical aspects of organolithium compounds are considered in two sections, dedicated to elemental analysis of lithium (Section in.A) and determination of the compounds as such (Section in.B). 

Also, analytical procedures were developed for the quantitative analysis of organolithium compounds. Fortunately these had the merit for our studies in being convenient, rapid, and not requiring any special apparatus or equipment beyond conventional laboratory glassware. 

The Restricted Vibrational Space (RVS) decomposition Scheme has been used in a quantitative analysis of the intermolecular forces which account for formation of aggregates/complexes of organolithium compounds the electrostatic contribution is always dominant and outweighs any disadvantage of distortion of the partners in complex formation. " ... 

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