Organic hydrogen adsorption properties

RowseU, J.L.C., and Yaghi, O.M. 2006. Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks. Journal of the American Chemical Society 128,1304—1315. 

Kubo, M., Ishiyama, K., Shimojima, A., and Okubo, T. (2012) Effect of organic groups on hydrogen adsorption properties of periodic mesoporous organosilicas. Microporous Mesoporous Mater., 147, 194-199. 

J. L. C. RowseU and O. M. Yaghi, Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal-Organic Frameworks, J. Am. Chem. Soc., Vol. 128, pp. 1304-1315, 2006. 

This proposal was based on adsorption properties of Ti sites, on the reactivity behaviour of organic and inorganic peroxides and on the smooth formation of cyclic structures in hydroperoxides and other compounds. In the alternative species, based on quantum chemical studies, the hydroperoxide group was T] coordinated and did not require stabilization (Figure 18.1b) [72]. In another proposal, also based on DFT calculations, coordination and hydrogen bonding with a protic molecule coexist in the same structure (Figure 18.1c) [73, 74]. 

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