Open loop systems oxidation

Where open-loop systems are unavoidable, mine water should be circulated through heat pumps and exchangers in such a way as to minimize contact with atmospheric Oz, which promotes oxidation of Fe2+ to poorly soluble Fe3+. Also consideration should be given to pressurized systems, in which down-mine pressures are maintained as far as possible, to hinder degassing of, for example, C02. Such degassing may elevate pH and promote precipitation of Fe-oxyhydroxides or carbonate scales. 

Nitrite formulations are employed for both hot and cold water closed loops (and also occasionally for open cooling systems). Unfortunately, nitrite is easily oxidized to nitrate and is very susceptible to microbiological attack (by Nitrobacter agilis and other microorganisms). Nevertheless, it is a good low-cost passivating inhibitor. 

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