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One-particle groups

There are no states in that produce a one-dimensional representation of S0(25, R) and we conjecture that there are no subgroups of SO(2s, R), which are not subgroups of U N) XU 2s - N) or USp(25), that produce one-dimensional representations on Thus there are no CS manifolds in based on subgroups of 80(2, R) that cannot be described in terms of U N) X U 2s - N) or USp(25) CSs. [Pg.113]

We show by construction in Section 4 that the group USp(2s) and its subgroups do have one-dimensional representations in and one [Pg.114]

The index set cr, tui. tUp, is determined by the array c,ll s of canonical coefficients [34] of the geminal that determines the AGP state according to [Pg.114]

We now consider a few particular examples. If all the coefficients are different and non-zero, so that = 0, w = 0, p = 0, the isotropy subgroup is [Pg.114]

If 17 0 the reference AGP is produced by a degenerate geminai and the action of the associated coset only produces a sub-manifold of AGP states, all of which correspond to geminals that have the same null space (see Appendix A) as the reference AGP. [Pg.115]


In Section 2 we discuss the Lie algebra structure of Fermi-Fock space, which is the direct sum of all of the state spaces W, in Section 3 we will describe the possible decompositions of the Lie algebra u 2s) of U 2s), the one-particle group associated with, and thus the factorizations of U (25) that lead to manifolds of CSs in that can be based on U 2s). In Section 4 we study in detail the forms of AGP CSs. We also show how the CS construction applied to the unitary group of A-electron space can reproduce the familiar configurational interaction expansion. We conclude with a summary and discussion in Section 5. [Pg.111]

All CS manifolds in based on the one-particle group U 2s) are families of AGP states, some of these manifolds are irreducible Riemannian manifolds and correspond to cosets formed by the maximal compact subgroups U 2M) XU 2s - 2M) and USp(25), while others are reducible and correspond to non-maximal compact subgroups USp(2basic physical properties, e.g., U 2M) X U 2s - 2M) invariant manifold describes uncorrelated IPSs, the USp(2s) invariant manifold describes highly correlated extreme AGP states that are superconducting, while the USp(2a>i) X X USp(2wp) X SU(2) X SU(2 ) invariant manifold for general (Oj,..., cr, describe intermediate types of correlation and linear response properties, see, for a particular example. Ref. [35], most of which have not been explored in any depth. [Pg.115]

Co-representation matrices explicit forms, 733 multiplication of, 731 of the nonunitary group, 732 Corliss, L. M., 757 Corson, E. M., 498 Coulomb field Dirac equation in, 637 Coulomb gauge, 643,657,664 Counting functions, 165 Covariance matrix, 160 Covariant amplitude of one-particle system, 511 of one, two, etc. particle systems, 511... [Pg.771]

There has been some speculation on the packing density of surface silanol groups. Her (180) estimated the number of silicon atoms in the surface as 7.85/100 A. He assumed that each silicon atom carries one OH group. However, it is more likely that only half of the silicon atoms have free valences protruding from the particle surface. Otherwise, each particle would be coated by a (HjSijOj) layer which had no bonding to the particle itself. Thus, a value of 3.93 OH groups per 100 A seems more likely. [Pg.227]

Due to Heisenberg s uncertainty and Pauli s exclusion principles, the properties of a multifermionic system correspond to fermions being grouped into shells and subshells. The shell structure of the one-particle energy spectrum generates so-called shell effects, at different hierarchical levels (nuclei, atoms, molecules, condensed matter) [1-3]. [Pg.53]

Whatever method is used in practice to generate spin eigenfunctions, the construction of symmetry-adapted linear combinations, configuration state functions, or CSFs, is relatively straightforward. First, we note that all the methods we have considered involve 7V-particle functions that are products of one-particle functions, or, more strictly, linear combinations of such products. The application of a point-group operator G to such a product is... [Pg.145]

A further complication is the basic assumption of the statistical methods that source profiles neither change during air transport nor with time. Therefore they cannot be applied strictly to secondary aerosol constituents formed in the atmosphere by gas-to-particle conversion processes. Still, the secondary aerosol constituents tend to be grouped into one source group since they have a common source , i.e. formation in air triggered by solar irradiation. [Pg.200]


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